Conductimetric titration of a saline solution

Ten millilitres of saline diluted ten times, sixty millilitres of water so the cell is covered, and silver nitrate at 0.0100 mol/L in the burette. Each silver ion removes a chloride ion as white silver chloride; the conductivity drifts down, then climbs once silver is in excess. The break is the equivalence, and it gives the salt content of the bottle.

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σ mS/cmVolume delivered mL

Each step has a button in the rail; the bench makes the gesture. You can also grab the bottle and carry it yourself. Click a name or an object to look closer, double-click the bench to step back. Slide the view with shift + scroll, the arrow keys, a right-button drag or two fingers.

Step 1 of 13
  1. 1
    Get ready

    Goggles and gloves: silver nitrate stains skin black and irritates the eyes.

  2. 2
    Fill the burette
  3. 3
    Read the conductivity
  4. 4
    Predict the curve
  5. 5
    Deliver 8 mL
  6. 6
    What do you see at 8 mL?
  7. 7
    Read the conductivity at 8 mL
  8. 8
    Go to 25 mL
  9. 9
    Read the shape
  10. 10
    Read Veq on the graph
  11. 11
    Back to the label
  12. 12
    Why those slopes?
  13. 13
    Label checked

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